QUANTITATIVE DATA ON SOME OXIDATIVE ADDITION-REACTIONS AND ON THE LEWIS BASICITY OF IRI[(C6H5)3P]2(CO)CL

被引：16

作者：

DRAGO, RS

NOZARI, MS

KLINGER, RJ

CHAMBERLAIN, CS

机构：

[1] Wm. A. Noyes Laboratory, School of Chemical Sciences, University of Illinois, Urbana

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 05期

关键词：

D O I：

10.1021/ic50195a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hydrogen-bonding interaction involving a d8 transition-metal donor is reported and the enthalpy of adduct formation determined. This data coupled with the enthalpy of formation of the SO2 adduct permits a tentative characterization of this donor in terms of the E and C model. The donor is contrasted with organic donors. Average metal-halogen bond energies for the Ir(III)-Br and Ir(III)-I bonds in the oxidative addition product of the titled compound are reported. © 1979, American Chemical Society. All rights reserved.

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页码：1254 / 1256

页数：3

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