HEADSPACE ANALYSIS OF 1,4-DIOXANE IN PRODUCTS CONTAINING POLYETHOXYLATED SURFACTANTS BY GC-MS

被引：25

作者：

RASTOGI, SC

机构：

[1] National Environmental Research Institute, Division of Environmental Chemistry, Ministry of Environment, Søborg, DK-2860

来源：

CHROMATOGRAPHIA | 1990年 / 29卷 / 9-10期

关键词：

1,4-dioxane; Gas chromatography-mass spectrometry; Headspace analysis; Polyethoxylated surfactants;

D O I：

10.1007/BF02261391

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A headspace, gas chromatography-mass spectrometric (GC-MS) method for the identification and quantitation of 1,4-dioxane in polyethoxylated surfactants is described. An isotope dilution method employing 1,4-d8-dioxane has been used for the quantitation of 1,4-dioxane which is based on the determination of the molecular ion (mass 88) by MS. The detection limit of the method was 0.3 ppm 1,4-dioxane. 82% of the cosmetic products investigated were found to contain 0.3-96 ppm 1,4-dioxane, and 85% of the products for dish washing investigated contained 1.8-65 ppm 1,4-dioxane. © 1990 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH.

引用

页码：441 / 445

页数：5

共 12 条

[1]

BIRKEL TJ, 1979, J ASSOC OFF ANA CHEM, V62, P931

[2]

BLACK DB, 1983, J ASSOC OFF ANA CHEM, V66, P180

[3]

CLAYTON GD, 1982, PATTYS IND HYGIENE T, V2, P3947

[4] The toxicity to animals of 1 4 dioxan [J].

Fairley, A ;

Linton, EC ;

Ford-Moore, AH .

JOURNAL OF HYGIENE, 1934, 34 (04) :486-501

[5]

FISHBEIN L, 1979, STUDIES ENV SCI POTE, V4, P481

[6] 3 INDUSTRIAL SOLVENTS INVESTIGATED FOR TUMOR PROMOTING ACTIVITY IN THE RAT-LIVER [J].

LUNDBERG, I ;

HOGBERG, J ;

KRONEVI, T ;

HOLMBERG, B .

CANCER LETTERS, 1987, 36 (01) :29-33

[7]

LUNDBERG S, 1982, NORDISKA EKSPERTGRUP, P6

[8]

RUMENAPP J, 1987, GERICHTE CHEM, V41, P59

[9]

WENNINGER JA, 1980, ASSOC FOOD DRUG OFF, V44, P145

[10]

1978, NCICGTR80 CARC TECHN

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