SYNTHESIS AND ABSOLUTE-CONFIGURATION OF DRIM-9(11)-EN-8-OLS FROM ASPERGILLUS-ORYZAE

被引：14

作者：

DOMINGUEZ, G ^{[1
]}

HUESORODRIGUEZ, JA ^{[1
]}

DELATORRE, MC ^{[1
]}

RODRIGUEZ, B ^{[1
]}

机构：

[1] CSIC,INST QUIM ORGAN,JUAN CIERVA 3,E-28006 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 36期

关键词：

DRIMANE SESQUITERPENOIDS; ABSOLUTE CONFIGURATION; SYNTHESIS FROM (+)-ROYLEANONE; ALLYL SELENOXIDES;

D O I：

10.1016/S0040-4039(00)92302-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantiomeric synthesis of the drimane sesquiterpenes 1 and 2 has been achieved starting from the diterpene (+)-royleanone (3) via its derivative 5. This result establishes that the natural sesquiterpenes isolated from Aspergillus oryzae have a normal absolute stereochemistry, like steroids. This conclusion is opposite to other data recently published.

引用

页码：4765 / 4768

页数：4

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