ATROPISOMERISM IN ASYMMETRIC CIS-DIPHOSPHINE ARYLPLATINUM COMPLEXES

被引：21

作者：

ALCOCK, NW ^{[1
]}

BROWN, JM ^{[1
]}

PEREZTORRENTE, JJ ^{[1
]}

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 03期

关键词：

PLATINUM; METAL-ARYLS; ROTATIONAL BARRIER; NMR;

D O I：

10.1016/S0040-4039(00)74139-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Slow rotation about the M-aryl bond has been observed in several cis-P2PtArX complexes; the X-ray crystal structure of a single rotamer of (R)-[BINAP]PtAr2 (Ar = 0-C6H4OMe) is reported.

引用

页码：389 / 392

页数：4

共 20 条

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