GRAFT-COPOLYMERS AND COMPOSITES OF POLY(METHYL METHACRYLATE) AND POLYPYRROLE .1.

被引：44

作者：

STANKE, D ^{[1
]}

HALLENSLEBEN, ML ^{[1
]}

TOPPARE, L ^{[1
]}

机构：

[1] MIDDLE EAST TECH UNIV,DEPT SCI,ANKARA 06531,TURKEY

来源：

SYNTHETIC METALS | 1995年 / 72卷 / 01期

关键词：

GRAFT COPOLYMERS; COMPOSITES; POLY(METHYL METHACRYLATE); POLYPYRROLE;

D O I：

10.1016/0379-6779(94)02322-P

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Pyrrole (Py) 2 was grafted onto a poly(methyl methacrylate) (PMMA) backbone which already contained the Py moiety within, via oxidative polymerization with FeCl3 in nitromethane. Graft copolymers 3 with very low Py amounts were soluble but they became rapidly insoluble with increasing Py content due to the formation of long Py sequences. The properties of the graft copolymers 3, as well as of films cast from the reaction mixture, depended on several reaction conditions. The products 3 were characterized using elemental analysis, UV-Vis, gel permeation chromatography and differential scanning calorimetry.

引用

页码：89 / 94

页数：6

共 14 条

[1] SYNTHESIS OF POLYACETYLENE BLOCK GRAFT-COPOLYMERS [J].