BEHAVIOUR OF CARRIER-FREE 32P FORMED IN ELEMENTARY SULPHUR BY NUCLEAR REACTION 32S(N,P) 32P IN SOME ISOTOPIC EXCHANGE REACTIONS

被引：1

作者：

BEBESEL, PI

TURCANU, CN

机构：

[1] Institute of Atomic Physics, Bucharest

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 02期

关键词：

D O I：

10.1016/0022-1902(68)80463-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isotopic exchange reactions of carrier-free 32P formed in elementary sulphur, with such compounds as PCl3, POCl3, PSCl3 were studied. Exchange was observed in the case of POCl3 and PSCl3. It was catalysed by AlCl3. Only the radiophosphorus atoms present in deaerated sulphur targets show this exchange. This study presents further evidence that two chemical states of carrier-free 32P may be present in irradiated sulphur targets, depending on the presence or absence of oxygen included in the crystalline lattice of irradiated sulphur. © 1968.

引用

页码：369 / &

共 11 条

[1] BEBESEL PI, 1967, REV ROUM CHIM, V12, P437
[2] BEBESEL PI, 1967, REV ROUM CHIM, V12, P95
[3] CHEMICAL STATES OF RADIOPHOSPHORUS FORMED IN ELEMENTARY SULPHUR BY NUCLEAR REACTION 32S(N P)32P
BEBESEL, PI
TURCANU, CN
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (04): : 891 - &
[4] BEBESEL PI, UNPUBLISHED WORKS
[5] BEBESEL PI, 1967, RADIOCHIM ACTA, V7, P201
[6] CHEMICAL SPECIES PRODUCED BY NEUTRON IRRADIATION OF PHOSPHORUS TRICHLORIDE
CONN, PK
HEIN, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (01) : 60 - 63
[7] PREPARATION OF 32P LABELLED COMPOUNDS FROM CARRIER FREE 32P
DUBINI, M
PERUCCA, GP
[J]. JOURNAL OF LABELLED COMPOUNDS, 1965, 1 (04): : 308 - &
[8] ON THE CHEMICAL STATE OF P-32 AND P-33 IN A SULPHUR TARGET
NILSSON, G
[J]. ACTA CHEMICA SCANDINAVICA, 1956, 10 (01): : 94 - 105
[9] NEUTRON AND GAMMA-IRRADIATION OF PHOSPHORUS TRICHLORIDE
SETSER, DW
MOSER, HC
HEIN, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (16) : 4162 - 4165
[10] 1962, INORGANIC ISOTOPIC S, P153

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