ELECTRONIC SPECTRA OF CARBONYL COMPOUNDS .2. SPECTRA AND MOLECULAR ORBITAL CALCULATIONS FOR TYPICAL ACETYL AND BENZOYL SYSTEMS

被引：33

作者：

YATES, K

KLEMENKO, SL

CSIZMADIA, IG

机构：

[1] Department of Chemistry, University of Toronto, Toronto, Ont.

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 04期

关键词：

D O I：

10.1016/0584-8539(69)80051-6

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The electronic and steric effects of a substituent X in typical acetyl (CH3COX) and benzoyl (PhCOX) systems have been investigated experimentally (ultraviolet spectra) and theoretically (LCAO-MO calculations). The good semiquantitative agreement between calculated and observed results (based on a study of twenty-six different carbonyl derivatives) allows some general conclusions to be drawn concerning the effects of substituents on the electronic transitions. © 1969.

引用

页码：765 / +

页数：1

共 28 条

[1] ELECTRONIC SPECTRA OF CARBONYL COMPOUNDS .I. SPECTRA AND MOLECULAR ORBITAL CALCULATIONS FOR ALPHA-SILYL AND ALPHA-GERMYL KETONES [J].