OXIDATION OF HYDROCARBONS WITH BENZYL(TRIETHYL)AMMONIUM PERMANGANATE

被引：55

作者：

SCHMIDT, HJ ^{[1
]}

SCHAFER, HJ ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-4400 MUNSTER,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1002/anie.197900681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of CH bonds by permanganate in organic solvents becomes possible on use of the salt benzyl(triethyl)ammonium permanganate. Hydrocarbons such as 1 and 2 are oxidized mainly to ketones and tertiary alcohols, repectively, while ethers such as 3 give esters. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：68 / 69

页数：2

共 9 条

[1] CLAUSSEN T, 1977, THESIS U MUNSTER
[2] DRY OZONATION - METHOD FOR STEREOSELECTIVE HYDROXYLATION OF SATURATED COMPOUNDS ON SILICA-GEL
COHEN, Z
KEINAN, E
MAZUR, Y
VARKONY, TH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (14) : 2141 - 2142
[3] KINETIC STUDIES OF THE OXIDATION OF AROMATIC COMPOUNDS BY POTASSIUM PERMANGANATE .3. ETHYLBENZENE
CULLIS, CF
LADBURY, JW
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1955, : 2850 - 2854
[4] GOKEL GW, 1976, SYNTHESIS-STUTTGART, P168
[5] KLEIN H, 1975, TETRAHEDRON LETT, P4249
[6] LEE DG, 1969, OXIDATION, V1, P3
[7] TETRABUTYLAMMONIUM PERMANGANATE - EFFICIENT OXIDANT FOR ORGANIC SUBSTRATES
SALA, T
SARGENT, MV
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (06) : 253 - 254
[8] CROWN POLYETHER CHEMISTRY - POTASSIUM PERMANGANATE OXIDATIONS IN BENZENE
SAM, DJ
SIMMONS, HE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (11) : 4024 - &
[9] STEWART R, 1965, OXIDATION ORGANIC A, P39

← 1 →