PREPARATION OF TRIALUMINUM TRIBORON HEPTAKIS(DIMETHYLAMINO)PENTAHYDRIDE

被引：12

作者：

HALL, RE

SCHRAM, EP

机构：

[1] Evans Chemical Laboratory, Ohio State University, Columbus

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 02期

关键词：

D O I：

10.1021/ic50072a017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of bis(trimethylamine)-alane, [(CH3)3N]2AlH3, with tetrakis(dimethylamino)diborane(4), [(CH3)2N]4B2, results in the formation of the following known compounds: H2, (CH3)3N, [(CH3)2NBH2]2, [(CH3)2N]2BH, and (CH3)3NBH3. In addition, a new species was prepared, Al3B3[N(CH3)2]7H5, which most likely contains three B-Al bonds. Characterization of this new compound is discussed. © 1969, American Chemical Society. All rights reserved.

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页码：270 / &

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