SYNTHESIS OF THE PYRROLIZIDINE BASE, (+/-)-SUPINIDINE

被引：30

作者：

ROBINS, DJ

SAKDARAT, S

机构：

[1] Department of Chemistry, University of Glasgow

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 07期

关键词：

D O I：

10.1039/p19790001734

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the conversion of saturated pyrrolizidine esters into their 1,2-didehydro-derivatives has been established. The unsaturation is introduced by phenylselenenylation α to an ester function, followed by fragmentation of the derived seleno-derivative. Using this technique, (±)-supinidine (1) has been synthesized.

引用

页码：1734 / 1735

页数：2

共 22 条

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