CONVERSION OF MONO-ALKYL OLEFINS TO 1,1-DIALKYL OLEFINS BY REACTION WITH BIS(CYCLOPENTADIENYL)TITANIUM DICHLORIDE TRIALKYLALUMINUM

被引：22

作者：

BARBER, JJ ^{[1
]}

WILLIS, C ^{[1
]}

WHITESIDES, GM ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 20期

关键词：

D O I：

10.1021/jo01334a042

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of certain monoalkyl olefins with a reagent generated by mixing bis(cyclopentadienyl)titanium dichloride and a trialkylaluminum compound provides a single-step procedure for preparing 1,1-dialkyl olefins. © 1979, American Chemical Society. All rights reserved.

引用

页码：3603 / 3604

页数：2

共 10 条

[1] BROWN HC, 1975, ORGANIC SYNTHESES VI, pCH9
[2] DYACHKOVSKII FS, 1975, COORDINATION POLYM, P199
[3] ORGANOMETALLIC COMPOUNDS OF GROUP-3 .33. POLAR AND STEREOCHEMICAL FACTORS IN CARBALUMINATION OF OLEFINS - ADDITION OF TRIPHENYLALUMINUM TO 6-SUBSTITUTED BENZONORBORNADIENES
EISCH, JJ
BURLINSON, NE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (03) : 753 - 761
[4] ORGANOMETALLIC COMPOUNDS OF GROUP-3 .35. STEREOSPECIFIC REDUCTIVE ALKYLATION OF ACETYLENES BY SUCCESSIVE HYDRALUMINATION AND CARBODEMETALLATION
EISCH, JJ
DAMASEVITZ, GA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (12) : 2214 - 2215
[5] CONVENIENT PREPARATIONS OF 1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE AND 1-ETHYL-2,3,4,5-TETRAMETHYLCYCLOPENTADIENE
FEITLER, D
WHITESIDES, GM
[J]. INORGANIC CHEMISTRY, 1976, 15 (02) : 466 - 469
[6] SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS .8. DOUBLE METAL CATALYSIS IN CROSS-COUPLING REACTION AND ITS APPLICATION TO STEREO-SELECTIVE AND REGIOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS
NEGISHI, E
OKUKADO, N
KING, AO
VANHORN, DE
SPIEGEL, BI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) : 2254 - 2256
[7] NEGISHI E, 1977, J AM CHEM SOC, V99, P3170
[8] SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS .8. CONTROLLED CARBOMETALATION - REACTION OF ACETYLENES WITH ORGANOALANE-ZIRCONOCENE DICHLORIDE COMPLEXES AS A ROUTE TO STEREO-DEFINED AND REGIO-DEFINED TRISUBSTITUTED OLEFINS
VANHORN, DE
NEGISHI, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) : 2252 - 2254
[9] TRANSITION-METAL PROMOTED ALKYLATIONS OF UNSATURATED ALCOHOLS - METHYLATION AND ETHYLATION OF 3-BUTEN-1-OL USING TITANIUM TETRACHLORIDE-ORGANOALUMINUM SYSTEMS
YOUNGBLOOD, AV
NICHOLS, SA
COLEMAN, RA
THOMPSON, DW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 146 (03) : 221 - 228
[10] 1978, HALCON FELLOW

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