A GENERAL ENTRY TO RIGID SYSTEMS WITH ALTERNATINGLY ORTHOGONAL ARENE UNITS VIA DIELS-ALDER REACTIONS

被引：23

作者：

KONIG, B

HEINZE, J

MEERHOLZ, K

DEMEIJERE, A

机构：

[1] UNIV HAMBURG,INST ORGAN CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

[2] UNIV FREIBURG,INST PHYS CHEM,W-7800 FREIBURG,GERMANY

[3] UNIV GOTTINGEN,INST ORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [2.2]paracyclophanes 1 and 2 containing annelated furan units on the bridges can be prepared by retro-Diels-Alder reactions from tetrabromine[2.2]paracyclophane in a two-step procedure. On treatment with dehydro- and bisdehydroarenes they afford, after deoxygenation, novel polycyclenes such as 3 with alternating orthogonal arene units.

引用

页码：1361 / 1363

页数：3

共 11 条

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