ANION-EXCHANGE RESINS PREPARED FROM POLYSTYRENE CROSSLINKED VIA A FRIEDEL-CRAFTS REACTION

被引：22

作者：

BELFER, S

GLOZMAN, R

机构：

[1] Division of Membranes & Ion-Exchangers, Research & Development Authority, Ben-Gurion University of the Negev, Beer-Sheva

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1979年 / 24卷 / 10期

关键词：

D O I：

10.1002/app.1979.070241007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The preparation of anion exchange resins from polystyrene crosslinked via a Friedel–Crafts reaction is investigated. Chloromethylation of a highly swollen styrene–hexahydrotriacrylolyl‐s‐triazine copolymer with a mixture of chlorosulfonic acid and methylal is accompanied by the crosslinking of the initially flexible copolymer. The crosslinking efficiency is dependent on the conditions (temperature, nature of solvent) of chloromethylation and can be explained by cationic postpolymerization of polystyrene or poly(benzylchloride), which takes place concurrently with the chloromethylation. Copyright © 1979 John Wiley & Sons, Inc.

引用

页码：2147 / 2157

页数：11

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