REACTIVITY OF PERFLUORO-N-ALKYL RADICALS - A HAMMETT STUDY OF HYDROGEN-TRANSFER FROM ARENE THIOLS

被引：7

作者：

DOLBIER, WR

RONG, XX

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)73397-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Hammett study of hydrogen atom abstraction by the perfluoro-n-heptyl radical is presented. Excellent correlation of the rates with sigma(+), with a rho(+) value of -0.56, provides important corroboration of the substantial influence of transition state polar effects on this unexpectedly slow process.

引用

收藏

页码：6225 / 6228

页数：4

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