THE STRUCTURE OF POLY(M-PHENYLENE) - A PREDICTION FROM SINGLE-CRYSTAL X-RAY STUDIES OF M-DECIPHENYL AND M-UNDECIPHENYL

被引：59

作者：

WILLIAMS, DJ ^{[1
]}

COLQUHOUN, HM ^{[1
]}

OMAHONEY, CA ^{[1
]}

机构：

[1] ICI CHEM & POLYMERS LTD,RUNCORN WA7 4QE,CHESHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001643

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-crystal X-ray diffraction studies of the oligomers m-deciphenyl and m-undeciphenyl, isolated chromatographically from low molecular mass poly(m-phenylene), reveal disordered but unequivocally helical chain-structures, from which the crystal and molecular structure of poly(m-phenylene) can be directly inferred.

引用

页码：1643 / 1644

页数：2

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