CHEMISTRY OF DINUCLEAR CARBONYL ANIONS .4. THIOCYANATE- AND CYANIDE-BRIDGED COMPLEXES

被引：71

作者：

RUFF, JK

机构：

[1] Rohm and Haas Company, Redstone Research Laboratories, Huntsville

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期

关键词：

D O I：

10.1021/ic50071a021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of either cyanide or thiocyanate ions with M(CO)6 (where M = Cr or W) produced, in addition to the mononuclear anions M(CO)5X-, dinuclear anions of the type M6(CO)10X-. Extension of this reaction to Fe(CO)5 resulted in the preparation of the anions Fe(CO)4NCS-, Fe(CO)4CN-, and Fe2(CO)5CN-. The spectra of these materials are discussed in relation to their structure. © 1969, American Chemical Society. All rights reserved.

引用

页码：86 / &

共 19 条

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