DIASTEREOSELECTIVE DESULFURIZATION OF 5,6-DIHYDRO-1,4-DITHIINS - SYNTHESIS OF MUSCALURE FROM MUSCA-DOMESTICA L

被引：23

作者：

CAPUTO, R ^{[1
]}

PALUMBO, G ^{[1
]}

PEDATELLA, S ^{[1
]}

机构：

[1] UNIV NAPLES,DIPARTIMENTO CHIM ORGAN & BIOL,I-80134 NAPLES,ITALY

来源：

TETRAHEDRON | 1994年 / 50卷 / 24期

关键词：

D O I：

10.1016/S0040-4020(01)85249-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A procedure is reported for the chemo- and stereo-selective sulfur removal from 5,6-dihydro-1,4-dithiins which completes the pathway to synthesize cis configurated olefins from carbonyl compounds. A four step synthesis of (Z)-9-tricosene (muscalure) with the dithiin moiety serving as the penultimate olefin precursor is also reported as an example of the proposed synthetic strategy.

引用

页码：7265 / 7268

页数：4

共 12 条

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