MU(3)-OXO-TRIS[(TRIISOPROPYLPHOSPHINE)GOLD(I)] TETRAFLUOROBORATE

被引：20

作者：

ANGERMAIER, K

SCHMIDBAUR, H

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195003787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

mu(3)-Oxo-tris[(triisopropylphosphine)gold(I)] tetrafluoroborate, [Au3O(C9H21P)(3)]BF4, crystallizes with C-3 nu-symmetrical cations and anions. The cations show intramolecular Au ... Au bonding, but any intermolecular aggregation, as detected in other homologues, is prevented by the bulky phosphine ligands.

引用

收藏

页码：1793 / 1795

页数：3

相关论文

共 13 条

[1] THE SUPRAMOLECULAR STRUCTURES OF COMPLEX TRI[GOLD(I)]SULFONIUM CATIONS [J].

ANGERMAIER, K ;

SCHMIDBAUR, H .

CHEMISCHE BERICHTE, 1994, 127 (12) :2387-2391

[2] A NEW STRUCTURAL MOTIF OF GOLD CLUSTERING AT OXIDE CENTERS IN THE DICATION [AU6O2(PME3)6]2+ [J].

ANGERMAIER, K ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1994, 33 (10) :2069-2071

[3]

ENRAFNONIUS, 1989, CAD4 SOFTWARE

[4] MU-3-SULPHIDO-TRIS[TRIPHENYLPHOSPHINEGOLD(I)]HEXAFLUOROPHOSPHATE [J].

JONES, PG ;

SHELDRICK, GM ;

HADICKE, E .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (NOV) :2777-2779

[5]

NESMEYANOV AN, 1980, J ORGANOMET CHEM, V201, P343, DOI 10.1016/S0022-328X(00)92589-0

[6]

PEREVALOVA EG, 1980, IAN SSSR KH, P1455

[7] RELATIVISTIC EFFECTS IN STRUCTURAL CHEMISTRY [J].

PYYKKO, P .

CHEMICAL REVIEWS, 1988, 88 (03) :563-594

[8] LATE-TRANSITION-METAL MU-OXO AND MU-IMIDO COMPLEXES .6. GOLD(I) IMIDO COMPLEXES [J].

RAMAMOORTHY, V ;

SHARP, PR .

INORGANIC CHEMISTRY, 1990, 29 (18) :3336-3339

[9] ON TRIS[(TRIALKYLPHOSPHINE)GOLD(I)]OXONIUM TETRAFLUOROBORATES AND TRIS[(TRIPHENYLPHOSPHINE)GOLD(I)]SULFONIUM TETRAFLUOROBORATE [J].

SCHMIDBAUR, H ;

KOLB, A ;

ZELLER, E ;

SCHIER, A ;

BERUDA, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (09) :1575-1579

[10]

SHELDRICK GM, 1989, SHELXTL PLUS