ELECTROCHEMICAL STUDY OF THE PHOTOCATALYTIC OXIDATION OF METHANOL ON RUTILE

被引：31

作者：

MIYAKE, M

YONEYAMA, H

TAMURA, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, Yamadakami

来源：

JOURNAL OF CATALYSIS | 1979年 / 58卷 / 01期

关键词：

D O I：

10.1016/0021-9517(79)90239-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic oxidation of methanol and 2-propanol by oxygen on illuminated rutile catalysts was analyzed by electrochemical measurements, and the indication was obtained that the Wagner-Traud mechanism prevails in the photocatalytic oxidation of these alcohols; i.e., the oxidation reaction consists of the anodic oxidation of the alcohol and the cathodic reduction of either oxygen or a complex consisting of oxygen and an intermediate of oxidized alcohol. © 1979.

引用

页码：22 / 27

页数：6

共 26 条

[1] PHOTOADSORPTION AND PHOTOCATALYSIS AT RUTILE SURFACES .1. PHOTOADSORPTION OF OXYGEN [J].