A resonance theory of thermolecular recombination kinetics: H+H+M-H-2+M

被引：22

作者：

Roberts, R. E.

Bernsteln, R. B.

Curtiss, C. F.

机构：

[1] Univ Wisconsin, Theoret Chem Inst, Madison, WI 53706 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 06期

关键词：

D O I：

10.1016/0009-2614(68)80026-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theory is presented for three-body recombination which identifies the reaction complex as a small set of orbiting resonances. Calculations of the thermolecular rate constant for H + H - M agree with experiment and also predict a low-temperature maximum which is attributed to the quasibound state v = 14. j = 5.

引用

收藏

页码：366 / 368

页数：3

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