TETRAKIS(TRIMETHYLGERMYL)SILANE AND TRIS(TRIMETHYLGERMYL)SILYLLITHIUM

被引：9

作者：

BAINES, KM

MUELLER, KA

SHAM, TK

机构：

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 12期

关键词：

D O I：

10.1139/v92-368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrakis(trimethylgermyl)silane can be synthesized by the addition of four equivalents of trimethylgermyllithium to tetrachlorosilane. Treatment of tetrakis(trimethylgermyl)silane with methyllithium gives tris(trimethylgermyl)silyllithium, which was trapped with aqueous hydrochloric acid, chlorotrimethylsilane or methyl iodide to yield tris(trimethylgermyl)silane, tris(trimethylgermyl)(trimethylsilyl)silane, or methyltris(trimethylgermyl)silane, respectively. Chlorination of tris(trimethylgermyl)silane affords dichlorobis(trimethylgermyl)silane.

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页码：2884 / 2886

页数：3

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