6 INTERPENETRATING QUARTZ-LIKE NETS IN THE STRUCTURE OF ZNAU2(CN)(4)

被引：103

作者：

HOSKINS, BF ^{[1
]}

ROBSON, R ^{[1
]}

SCARLETT, NVY ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

CYANO COMPLEXES; GOLD COMPOUNDS; SOLID-STATE STRUCTURES; ZINC COMPOUNDS;

D O I：

10.1002/anie.199512031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiomorphic quartz‐like networks 1 assemble spontaneously from solutions containing ZnII, which acts as a tetrahedral node in the network, and [Au(CN)2]−, which functions as an approximately linear, very long Zn ⃛Zn connector. Six such independent networks, all with the same handedness, are intimately entangled. The circles in order of decreasing size represent Zn, Au, N, and C. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1203 / 1204

页数：2

共 15 条

[1]

ABRAHAMS SC, 1982, J CHEM PHYS, V76, P5485

[2] CRYSTAL-STRUCTURE OF GAPO4 AT 20-DEGREES-C, 500-DEGREES-C AND 750-DEGREES-C [J].