OFF-RESONANCE ROESY FOR THE STUDY OF DYNAMIC PROCESSES

被引：96

作者：

DESVAUX, H ^{[1
]}

BERTHAULT, P ^{[1
]}

BIRLIRAKIS, N ^{[1
]}

GOLDMAN, M ^{[1
]}

机构：

[1] CEA, CTR ETUD SACLAY, SERV PHYS ETAT CONDENSE, F-91191 GIF SUR YVETTE, FRANCE

来源：

JOURNAL OF MAGNETIC RESONANCE SERIES A | 1994年 / 108卷 / 02期

关键词：

D O I：

10.1006/jmra.1994.1114

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The method of off-resonance ROESY consists of studying relaxation in the presence of a strong off-resonance irradiation. Its theory is developed under very general assumptions and its advantages are described over more standard methods: suppression of HOHAHA transfers and possibility by the appropriate choice of the effective field to check the only existence of dipolar relaxation, to investigate internuclear dynamics, or to isolate the study of chemical exchange. Experimental illustrations are given for some of the predictions. (C) 1994 Academic Press, Inc.

引用

页码：219 / 229

页数：11

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