TIN OSMIUM CLUSTER FORMATION WITH A MONOMERIC TIN(II) ALKYL - THE FORMATION, CRYSTAL-STRUCTURE AND REACTIVITY OF [OS3(MU-H)SNR(CO)10], A FORMAL STANNYNE COMPLEX OF THE OSMIUM TRIANGLE (R = C(SIME3)2C5H4N-2)

被引：15

作者：

CARDIN, CJ

CARDIN, DJ

CONVERY, MA

DEVEREUX, MM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000687

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The monomeric tin(II) species SnR2 {R = C(SiMe3)2C5H4N-2} reacts with [Os3(H)2(CO)10] in hexane to give [Os3(mu-H)SnR(CO)10] 1 quantitatively; 1 is the first formal stannyne complex of the triosmium nucleus, in which the picoline nitrogen is coordinated to the tin atom, and which is itself also reactive, being a potential precursor to high nuclearity SnOs clusters.

引用

页码：687 / 688

页数：2

共 6 条

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