STEREOSELECTIVE CYCLIC CARBOLITHIATION OF ALKYNE DERIVATIVES - A STEREOSELECTIVE SYNTHESIS OF EXOCYCLIC ALKENES

被引：57

作者：

WU, GZ ^{[1
]}

CEDERBAUM, FE ^{[1
]}

NEGISHI, E ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(90)87016-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Trimethylsilyl)alkyne derivatives that are lithiated in the δ position via non-radical routes can cyclize in a stereoselective manner (≥96-98%) to give exocyclic alkenes containing five-membered carbocycles in high yields. © 1990.

引用

页码：493 / 496

页数：4

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