DIASTEREOSELECTIVE ADDITION OF METHYLCOPPER-BORON TRIFLUORIDE AND DIMETHYLCUPRATE-BORON TRIFLUORIDE REAGENTS TO (S)-(N-ALKYLIDENE)-1-PHENYLETHYLAMINES

被引：25

作者：

BOGA, C ^{[1
]}

SAVOIA, D ^{[1
]}

UMANIRONCHI, A ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,VIA SELMI 2,I-40126 BOLOGNA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)86316-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of methylcopper- and diemthylcuprate-boron trifluoride reagents with aldimines derived from (S)-1-phenylethylamine afford with good diastereoselectivity (S,S)-amines from aromatic imines, but the (R,S)-amine from an aliphatic imine. © 1990.

引用

页码：291 / 294

页数：4

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