PARTIAL HYDROGENATION - FROM ANTHRACENE TO CORONENE

被引：38

作者：

YALPANI, M

KOSTER, R

机构：

[1] Max-Planck-Institut Für Kohlenforschung, Mülheim An Der Ruhr, D-4330

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 04期

关键词：

Polycyclic arenes / Hydrogenation / Borane catalysts / Hydroarenes / Tetraalkyldiboranes(6);

D O I：

10.1002/cber.19901230412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduktion kondensierter Arene mit ‐Boranen. – Partielle Hydrierung: Anthracen bis Coronen Tetrapropyldiboran(6) (TPDB) katalysiert die Hydrierung polycyclisher Arene [z. B. Anthracen (A), Tetracen (TET), Pyren (PY), Perylen (PER) oder Coronen (C)] unter Wasserstoff‐Druck bei 200°C. In einigen Fällen können sehr hohe Ausbeuten an Hydroarenen erzielt werden [z. B. Tetrahydroanthracen (4H‐A), Octahydroanthracen (8H‐A), Dodecahydrotetracen (12H‐TET), Tetrahydropyren (4H‐PY), Hexahydroperylen (6H‐PER) oder Hexahydrocornen (6H‐C)]. Neben unterschiedlichen kleinen Mengen an Perhydroarenen bilden sich nach langer Reaktionszeit aus sämtlichen Arenen auch C – C‐Spaltungsprodukte. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

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页码：719 / 724

页数：6

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