PALLADIUM-CATALYZED SYNTHESIS OF POLY(P-PHENYLENEETHYNYLENE)S

被引：43

作者：

SOLOMIN, VA ^{[1
]}

HEITZ, W ^{[1
]}

机构：

[1] UNIV MARBURG,POLYMERE & WISSENSCH ZENTRUM MAT WISSENSCH,FACHBEREICH PHYS CHEM,W-3550 MARBURG,GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 01期

关键词：

D O I：

10.1002/macp.1994.021950128

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(p-phenyleneethynylene)s were obtained by reacting 1,4-dihaloarenes with 2-methyl-3-butyn-2-ol in a two-step one-pot process. In the first step a dihaloarene is reacted with two equivalents of 2-methyl-3-butyn-2-ol at room temperature in the presence of an aqueous base. For polycondensation a second equivalent of dihaloarene is added and reacted at 100-degrees-C. Soluble polymers with M(w)BAR of 1 - 2 . 10(4) were obtained. They show blue fluorescence.

引用

页码：303 / 314

页数：12

共 10 条

[1] ABINITIO EFFECTIVE HAMILTONIAN STUDY OF THE ELECTRONIC-PROPERTIES OF CONJUGATED POLYMERS [J].