BRIDGED POLYCYCLIC COMPOUNDS .57. PHOTOREARRANGEMENT OF 7-METHYLENEDIBENZOBICYCLO[2.2.2]OCTADIENE . PREPARATION AND PROPERTIES OF DIBENZOTRICYCLO[4.2.1.01,3]OCTADIENE

被引：19

作者：

CRISTOL, SJ

MAYO, GO

机构：

[1] Department of Chemisiry, University of Colorado, Boulder

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 08期

关键词：

D O I：

10.1021/jo01260a024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photorearrangement of 7-methylenedibenzobioyclo[2.2.2]octadiene (3) yields dibenzotricyclo[4.2.1.01,3]-nonadiene (4) whose structure was determined by spectroscopic and chemical means. Upon hydrogenation cyclopropane 4 gives 5-methyldibenzobicyclo[3.2.1]octadiene (12). Treatment of 4 with perchloric acid in acetic acid gives dibenzobicyclo[4 2.1]nona-2,7-dien-6-ol acetate (15). © 1969, American Chemical Society. All rights reserved.

引用

页码：2363 / &

共 18 条

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Alder, K
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[2] AUGUSTINE RL, 1965, CATALYTIC HYDROGENAT, P133
[3] LIQUID-SOLID AND CAPILLARY GAS-LIQUID CHROMATOGRAPHY OF INTERNAL OLEFIN ISOMERS
CHAPMAN, LR
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (12) : 2882 - &
[5] BRIDGED POLYCYCLIC COMPOUNDS .27. PROTON MAGNETIC RESONANCE SPECTRA OF SOME DIBENZOBICYCLO[3.2.1]OCTADIENES
CRISTOL, SJ
MOHRIG, JR
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (06) : 1956 - &
[6] BRIDGED POLYCYCLIC COMPOUNDS .44. STEREOCHEMISTRY OF CYCLOPROPANE RING FORMATION FROM SUBSTITUTED DIBENZOBICYCLO[3.2.1]OCTADIENES
CRISTOL, SJ
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[7] BRIDGED POLYCYCLIC COMPOUNDS .38. STEREOCHEMISTRY OF CYCLOPROPANE RING FORMATION FROM GAMMA-CHLOROSULFONES IN DIBENZOBICYCLO[3.2.1]OCTADIENE SYSTEM
CRISTOL, SJ
JARVIS, BB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (13) : 3095 - &
[8] BRIDGED POLYCYCLIC COMPOUNDS .46. STEREOCHEMISTRY OF A NUCLEOPHILIC CYCLOPROPANE RING OPENING
CRISTOL, SJ
JARVIS, BB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (23) : 5885 - &
[9] CRISTOL SJ, IN PRESS
[10] CRISTOL SJ, UNPUBLISHED WORK

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