KINETICS OF CHROMIUM(6)-OXALIC ACID REACTION

被引：17

作者：

DURHAM, DA

机构：

[1] Institute of Physical Chemistry, Kossuth Lajos University, Debrecen

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 11期

关键词：

D O I：

10.1016/0022-1902(69)80342-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of oxalic acid by chromic acid has been studied kinetically at low pH and constant ionic strength. It has been found that the rate of the reaction is the sum of the rates of decomposition of a mono- and a di-oxalato complex of chromium(VI), the overall rate-law being of the form Rate=(K[Ox2-]+K′[Ox2-]2[H]3[CrO4H-. © 1969.

引用

页码：3549 / &