DESULFURIZATION OF THIOANILIDES VIA PALLADIUM COMPLEXES

被引：6

作者：

ALPER, H

CURRIE, JK

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 168卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)83218-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thioanilides (ArNHCSR) react with disodium tetrachloropalladate at room temperature to give bidentate complexes of structural type [(ArNC(R)S)PdCl]2. These complexes are quantitatively converted to amides by wet dimethylsulphoxide at room temperature. The desulphurization of thioanilides can be effected catalytically as well. © 1979.

引用

页码：369 / 373

页数：5

共 7 条

[1] ORTHO-METALATION OF FERROCENE
ALPER, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) : C29 - C30
[2] IRON CARBONYL-COMPLEXES OF THIOUREAS AND THIOAMIDES
ALPER, H
CHAN, ASK
[J]. INORGANIC CHEMISTRY, 1974, 13 (01) : 225 - 232
[3] CHEMISTRY OF SULFUR-DONOR LIGAND ORTHO-METALATED IRON CARBONYL-COMPLEXES AND THIOLACTONES DERIVED THEREFROM
ALPER, H
ROOT, WG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (15) : 4251 - 4257
[4] CYCLOMETALATION REACTIONS
BRUCE, MI
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (02): : 73 - 86
[5] 6-MEMBERED ORTHO-METALLATED RING-SYSTEMS
CAMERON, ND
KILNER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (16) : 687 - 688
[6] REACTIVITY OF COORDINATED LIGANDS .15. FORMATION OF COMPLEXES CONTAINING GROUP V DONOR ATOMS AND METAL-CARBON SIGMA BONDS
COCKBURN, BN
HOWE, DV
KEATING, T
JOHNSON, BFG
LEWIS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (04): : 404 - 410
[7] REACTIVITY OF CYCLOPALLATATED COMPOUNDS .3. REACTION WITH GROUP V DONOR ATOMS LIGANDS
DEHAND, J
PFEFFER, M
ZINSIUS, M
[J]. INORGANICA CHIMICA ACTA, 1975, 13 (03) : 229 - 232

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