A UNIQUE EXAMPLE OF AN OCTAHEDRAL IRON(II) COMPLEX CONTAINING 4 TRIFLATE ANIONS AND 2 NITRILE-LIKE ORGANOMETALLIC CATIONS

被引：15

作者：

BUSETTO, L ^{[1
]}

ZANOTTI, V ^{[1
]}

BORDONI, S ^{[1
]}

CARLUCCI, L ^{[1
]}

ALBANO, VG ^{[1
]}

BRAGA, D ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 06期

关键词：

D O I：

10.1039/dt9920001105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The action of MeSO3CF3 on [Fe2(cp)2(CO)2(mu-CO){mu-C(CN)SMe}] 1 (cp = eta(5)-C5H5) yields [Fe2(cp)2-(CO)2(mu-CO){mu-C(CN)SMe2}[SO3CF3] 2. The sulphonium cation is also obtained, trapped in the unusual triflate complex [Fe(OSO2CF3)4{Fe2(cp)2(CO)2(mu-CO)[mu-C(CN)SMe2]}2] 3, by treating the thiolcarbamate [Fe2(cp)2(CO)2(mu-CO){mu-C(CN)N(Me)C(O)SMe}] 4 with MeSO3CF3. The X-ray crystal structure of 3 shows the iron(II) centre co-ordinated by four O-bonded triflate anions and by two, mutually trans-disposed, N-co-ordinated organometallic cations in an octahedral geometry.

引用

页码：1105 / 1109

页数：5

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