DICATION SALT OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE - PREPARATION AND CRYSTAL-STRUCTURE OF BEDT-TTF(CLO4)2

被引：44

作者：

ABBOUD, KA ^{[1
]}

CLEVENGER, MB ^{[1
]}

DEOLIVEIRA, GF ^{[1
]}

TALHAM, DR ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 20期

关键词：

D O I：

10.1039/c39930001560

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrocrystallization of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) in an oxidizing solvent medium yields BEDT-TTF (ClO4)2, which is the first example of a salt in which BEDT-TTF is present only as the dication; bond length data from an X-ray structure determination of BEDT-TTF(ClO4)2 are used as a standard for assigning the +2 oxidation state to BEDT-TTF molecules in mixed-valent cation-radical salts.

引用

页码：1560 / 1562

页数：3

共 33 条

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