THE RELIABILITY OF FREE-ION YIELD IN PHOTOINDUCED ELECTRON-TRANSFER REACTIONS - THE MODEL SYSTEM 9,10-DICYANOANTHRACENE BIPHENYL IN ACETONITRILE

被引：27

作者：

VAUTHEY, E ^{[1
]}

PILLOUD, D ^{[1
]}

HASELBACH, E ^{[1
]}

SUPPAN, P ^{[1
]}

JACQUES, P ^{[1
]}

机构：

[1] ENSC,PHOTOCHIM GEN LAB,F-68200 MULHOUSE,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 215卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(93)89298-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A detailed study of the separation efficiency in the photoinduced electron transfer reaction between 9,10-dicyanoanthracene and biphenyl in acetonitrile is presented. Both transient absorption and photoconductivity indicate a separation efficiency of about 0.4. This value is in discrepancy with two of three previously reported efficiencies. The problems arising with too large donor concentrations and with the use of a secondary donor to determine the separation efriciency are discussed.

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页码：264 / 268

页数：5

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