LANGMUIR-BLODGETT-FILM AND 2ND-HARMONIC GENERATION OF A EUROPIUM HEMICYANINE COMPLEX, ME2NC6H4CH=CHC5H4NC16H33+EU(NTA)4-

被引:68
作者
ZHOU, DJ
HUANG, CH
WANG, KZ
XU, GX
ZHAO, XS
XIE, XM
XU, LG
LI, TK
机构
[1] BEIJING UNIV,STATE KEY LAB RARE EARTH MAT CHEM & APPLICAT,BEIJING 100871,PEOPLES R CHINA
[2] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA
[3] ACAD SINICA,INST PHOTOG CHEM,BEIJING 100101,PEOPLES R CHINA
关键词
D O I
10.1021/la00018a049
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An amphiphilic lanthanide complex, (E)-N-hexadecyl-4-[2-(4-(dimethylamino)phenyl)ethenyl]pyridinium tetrakis(beta-naphthanyltrifluoroacetone)europium (abbreviated as H-1-Eu(NTA)4), was synthesized and characterized. The film formation property is good and its vertical uniformity has been demonstrated by UV-vis spectra. The second-order molecular hyperpolarizability beta has been evaluated to be (6-9) X 10(-28) esu, which is about 1.5 times bigger than that of the iodide anion substituted complex.
引用
收藏
页码:1910 / 1912
页数:3
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