COUMARINS .9. COUMARINS OF SPHENOSCIADIUM CAPITELLATUM (A GRAY)

被引：19

作者：

LEE, KH

SOINE, TO

机构：

[1] Department of Medicinal Chemistry, College of Pharmacy, University of Minnesota, Minneapolis, Minnesota

[2] Department of Chemistry, University of California, Los Angeles, California

来源：

JOURNAL OF PHARMACEUTICAL SCIENCES | 1969年 / 58卷 / 06期

关键词：

Column chromatography—separation; Coumarins—Sphenosciadium capitellatum; IR spectrophotometry—structure; identity; Mass spectroscopy—molecular weight; NMR spectroscopy—structure; Paper chromatography—separation; S. capitellatum roots—coumarin extraction; UV spectrophotometry—structure;

D O I：

10.1002/jps.2600580605

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The aliphatic naphtha extract of the roots of Sphenosciadium capitellatum (A. Gray) has yielded isoimperatorin, phellopterin, imperatorin, oxypeucedanin, isopimpinellin, and a linear furanocoumarin, C17H16O5, which has been assigned the 5‐γ,γ‐dimethylallyloxy‐8‐methoxy psoralen structure on the basis of degradative and spectral studies. This linear furanocoumarin appears to be identical to cnidilin, recently isolated and characterized from Cnidium dubium (Schkuhr) Thell. The methanol extract yielded sucrose and the glycosidic coumarin, nodakenin, in excellent yield. Copyright © 1969 Wiley‐Liss, Inc., A Wiley Company

引用

页码：675 / &

共 21 条

[1] ARIMA J, 1929, B CHEM SOC JPN, V4, P16
[2] BUDZIKIEWICZ H, 1964, STRUCTURE ELUCIDATIO, V2, P259
[3] CHERONIS ND, 1963, IDENTIFICATION ORGAN, P284
[4] CITRUS BITTER PRINCIPLES .V. BOTANICAL DISTRIBUTION AND CHEMOTAXONOMY IN RUTACEAE
DREYER, DL
[J]. PHYTOCHEMISTRY, 1966, 5 (03) : 367 - &
[5] FURUYA T, 1967, CHEM PHARM BULL, V15, P1362
[6] COUMARINS .3. IDENTIFICATION OF LACTONE OF LEPTOTAENIA MULTIFIDA
GUPTA, PK
SOINE, TO
[J]. JOURNAL OF PHARMACEUTICAL SCIENCES, 1964, 53 (12) : 1543 - &
[7] HOUGH L, 1962, METHODS CARBOHYDRATE, V1, P315
[8] COUMARINS .10. SPECTRAL STUDIES ON SOME LINEAR FURANOCOUMARINS
LEE, KH
SOINE, TO
[J]. JOURNAL OF PHARMACEUTICAL SCIENCES, 1969, 58 (06) : 681 - &
[9] MATHIAS ME, 1945, NORTH AMERICAN FLORA, P202
[10] MUNZ PA, 1959, CALIFORNIA FLORA, V1029, P1029

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