CYCLIC SODIUM AND POTASSIUM (FLUOROSILYL)PHOSPHIDES - SYNTHESES AND CRYSTAL-STRUCTURES

被引：28

作者：

ANDRIANARISON, M ^{[1
]}

STALKE, D ^{[1
]}

KLINGEBIEL, U ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 01期

关键词：

(Fluorosilyl)phosphides; cyclic; /; Heterocycles; eight‐membered; Phosphides; alkali;

D O I：

10.1002/cber.19901230114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclic Sodium and Potassium (Fluorosily1)phosphides ‐ Syntheses and Crystal Structures (Di‐tert‐butylfluorosilyl)(mesityl)phosphine (1) reacts with sodium or potassium to give the alkali compounds [(CMe3)2SiFM(THF)2PC6H2Me3]2 (2: M = Na; 3: M = K). The crystal structures of the eight‐membered rings 2 and 3 have been determined. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：71 / 73

页数：3