THE ISOLATION OF (-)-SARCOPHYTOL A AND (+)-MARASOL FROM THE CARIBBEAN GORGONIAN PLEXAURA-FLEXUOSA

被引:16
作者
PENISTON, M
RODRIGUEZ, AD
机构
[1] Department of Chemistry, University of Puerto Rico
来源
JOURNAL OF NATURAL PRODUCTS | 1991年 / 54卷 / 04期
关键词
D O I
10.1021/np50076a014
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
The gorgonian Plexaura flexuosa from Puerto Rico was found to contain (1E, 3E,7E,11E)-(14R)-cembra-1,3,7,11-tetraen-14-ol [2], the (-)-antipode of the potent antitumor promoter (+)-sarcophytol A [5]. A new bicyclic oxa-bridged 2,5-dihydrofuran-containing cembranoid diterpene, (+)-marasol [4], was isolated as a minor constituent from samples of the same gorgonian. Their structures have been established through chemical and spectral studies.
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页码:1009 / 1016
页数:8
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