THE EFFICIENCY OF SINGLET OXYGEN GENERATION BY SUBSTITUTED NAPHTHALENES IN BENZENE - EVIDENCE FOR THE PARTICIPATION OF CHARGE-TRANSFER INTERACTIONS

被引:84
作者
MCGARVEY, DJ [1 ]
SZEKERES, PG [1 ]
WILKINSON, F [1 ]
机构
[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND
关键词
D O I
10.1016/0009-2614(92)80124-T
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An inverse correlation between the rate constant for oxygen quenching of the triplet state (k(q)T) and the efficiency of singlet oxygen generation (S(DELTA)) is established for a range of substituted naphthalenes in benzene. The participation of charge-transfer interactions are implicated on the basis that the only property which varies significantly with the substituent is the oxidation potential (E(M)ox) of the naphthalene derivative. Using published electrochemical data, correlations between S(DELTA), k(q)T and the free energy change for charge transfer (DELTAG(CT)) have been found with values of S(DELTA) and k(q)T ranging from 0.34 to 0.75 and from 5.0 X 10(9) to 1.2 X 10(9) M-1 s-1 for 1-methoxynaphthalene and 1-cyanonaphthalene, respectively.
引用
收藏
页码:314 / 319
页数:6
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