THE STRUCTURE AND BONDING OF NIDO-7,9-X2B9H9 (X = S OR SE)

被引:1
作者
NIDHUBHGHAILL, O
REED, D
SPALDING, TR
机构
[1] NATL UNIV IRELAND UNIV COLL CORK,DEPT CHEM,CORK,IRELAND
[2] UNIV LAUSANNE,INST CHIM MINERALE & ANALYT,CH-1005 LAUSANNE,SWITZERLAND
[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1016/S0277-5387(00)81469-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structure of nido-Se2B9H9 has been determined unambiguously to be the 7,9-isomer by ultra high-field (192.48 MHz) B-11 NMR spectroscopy. The He(I) PE spectrum of 7,9-Se2B9H9 is compared with the results of an MNDO MO calculation of the dithiaborane analogue 7,9-S2B9H9.
引用
收藏
页码:1977 / 1981
页数:5
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