CHARACTERIZATION OF OXIDIZED NICKEL (II) DIMETHYLGLYOXIME USING X-RAY PHOTOELECTRON-SPECTROSCOPY

被引：9

作者：

YOUNG, VY ^{[1
]}

CHANG, FC ^{[1
]}

CHENG, KL ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,KANSAS CITY,MO 64110

来源：

APPLIED SPECTROSCOPY | 1987年 / 41卷 / 06期

关键词：

METALLIC COMPOUNDS - Spectroscopic Analysis - SPECTROSCOPY; X-RAY; -; Applications;

D O I：

10.1366/0003702874447842

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

X-ray photoelectron spectroscopy has been used to determine the oxidation state of nickel in the oxidized nickel (II) dimethylglyoxime complex. Core level binding energies for the Ni(2p), N(1s), and O(1s) levels; the presence or absence of shake-up satellites on the Ni(2p) levels; and the analysis of intensity data are consistent only with an assignment of plus 3. Structures consistent with the data are proposed for both the solid- and the solution-phase complexes.

引用

页码：994 / 1000

页数：7

共 33 条

[1]

ALLEN GC, 1977, 7TH P INT VAC C 3RD, P959

[2]

BRUNCK O, 1908, Z ANGEW CHEM, V20, P1844

[3] ELECTRON-SPECTROSCOPY AND ADSORPTION STUDIES - CHEMICAL-SHIFTS IN X-RAY PHOTOELECTRON AND AUGER-SPECTRA FOR MONOLAYER ADSORPTION [J].