VANADIUM(II) PROMOTED DIASTEREOSELECTIVE AND ENANTIOSELECTIVE INTERMOLECULAR PINACOL CROSS COUPLING

被引：22

作者：

ANNUNZIATA, R ^{[1
]}

CINQUINI, M ^{[1
]}

COZZI, F ^{[1
]}

GIARONI, P ^{[1
]}

机构：

[1] DIPARTIMENTO CHIM ORGAN & IND,MILAN,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 06期

关键词：

D O I：

10.1016/0957-4166(90)90032-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cross coupling reaction promoted by [V2Cl3(THF)6]2[Zn2Cl6] of some aliphatic aldehydes with an aromatic aldehyde bearing a chiral auxiliary occurs in a stereocontrolled fashion to give syn 1,2- diols in diastereoisomeric ratios up to 91:9 and enantiomeric excesses up to 84%. © 1990.

引用

页码：355 / 358

页数：4

共 15 条

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