UNUSUAL KINETICS FOR THE HYDROBORATION OF ALKENES WITH 9-BORABICYCLO[3.3.1]NONANE

被引：30

作者：

BROWN, HC

SCOUTEN, CG

WANG, KK

机构：

[1] Richard B. Wetherill Laboratory, Purdue University, West Lafayette

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 14期

关键词：

D O I：

10.1021/jo01328a061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Kinetics of the reaction of dimeric 9-borabi-cyclo[3.3.1]nonane with representative alkenes establishes that hydroboration proceeds through prior dissociation of the dimer into monomer, leading to simplified kinetic expressions, 퓀1[(9-BBN)2] for reactive alkenes and 퓀3/2-[(9-BBN)2]½ [alkene] for less reactive alkenes. © 1979, American Chemical Society. All rights reserved.

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页码：2589 / 2591

页数：3

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