DICHLOROCARBENE ADDITION TO TRICARBONYLIRON COMPLEXES OF POLYENES

被引：17

作者：

TAYLOR, GA

机构：

[1] Department of Chemistry, University of Sheffield

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 07期

关键词：

D O I：

10.1039/p19790001716

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dichlorocarbene adds to the unco-ordinated double bonds in the tricarbonyliron complexes of cycloheptatriene and myrcene to give (2) and (5) respectively. Copper(II) oxidation of (5) liberates the ligand (6). The tricarbonyliron complexes of ergosteryl acetate (11) and cyclo-octatetraene (12) fail to react with dichlorocarbene. The possibility of aromatic character in the organic ligand in (12) is discussed.

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页码：1716 / 1719

页数：4

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