MAGNETIC-ANISOTROPY OF CUBIC IRON-BASED DILUTED MAGNETIC SEMICONDUCTORS

Iron-based diluted magnetic semiconductors having the cubic zinc-blende structure display an unusual response to external magnetic fields. For low fields, B, the magnetic susceptibility is isotropic, as expected for cubic crystals. However, when the magnetic field is sufficiently high so that the Zeeman energy cannot be neglected in comparison to the spacing of the low-lying levels of Fe2+ (owing to the spin-orbit interaction), the nonlinear magnetization exhibits a striking anisotropy. This phenomenon is related to the Van Vleck paramagnetism primarily due to the nature of the ground state of the (3d)6 configuration of Fe2+, namely, a singlet. This paper is concerned with Fe2+ in a tetrahedral environment and the concomitant Van Vleck type of paramagnetism. We present an analytic investigation of the magnetic moment of an Fe2+ ion in a T(d) field. In this approach the spin-orbit interaction and the Zeeman energy are treated as small compared to the crystal-field splitting but are themselves regarded as comparable. We obtain expressions for the effective number of Bohr magnetons per ion for B along the < 001 > and < 111 > directions. The anisotropy of this quantity is of the order of 15% at liquid-helium temperatures in a magnetic field of 150 kG. Corrections proportional to the ratio of the spin-orbit interaction and the crystal-field splitting are evaluated in first order.