SYNTHESIS, STRUCTURE AND LIGAND-CENTERED REDUCTION OF AN ORTHOMETALLATED COMPLEX OF PALLADIUM CONTAINING 2 PHOSPHAALKENE GROUPS

被引：47

作者：

JOUAITI, A

GEOFFROY, M

TERRON, G

BERNARDINELLI, G

机构：

[1] UNIV GENEVA,DEPT PHYS CHEM,30 QUAI ERNEST ANSERMET,CH-1211 GENEVA,SWITZERLAND

[2] UNIV GENEVA,CRYSTALLOG LAB,CH-1211 GENEVA,SWITZERLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel ligand containing two phosphaalkene moieties has been synthesized, which forms a palladium(II) complex whose crystal structure has been determined and whose reduction has been shown, by EPR spectroscopy, to take place on the ligand rather than on the metal.

引用

收藏

页码：155 / 156

页数：2

相关论文

共 22 条

[1] SYNTHESES OF ETA-1-PHOSPHA-ALKENE AND ETA-2-PHOSPHA-ALKENE TRANSITION-METAL COMPLEXES AND THE 1ST EXAMPLES OF COMPLEXES CONTAINING ONLY LIGATED PHOSPHA-ALKENES AND PHOSPHA-ALKYNES [J].

ALRESAYES, SI ;

KLEIN, SI ;

KROTO, HW ;

MEIDINE, MF ;

NIXON, JF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (17) :930-932

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] LOW COORDINATED PHOSPHORUS-COMPOUNDS .12. DIELS-ALDER REACTIONS OF PHOSPHAALKENES [J].

APPEL, R ;

KORTE, S ;

HALSTENBERG, M ;

KNOCH, F .

CHEMISCHE BERICHTE-RECUEIL, 1982, 115 (11) :3610-3617

[4] PHOSPHA-ALKENES AND PHOSPHA-ALKYNES, GENESIS AND PROPERTIES OF THE (P-P)PI-MULTIPLE BOND [J].

APPEL, R ;

KNOLL, F ;

RUPPERT, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (09) :731-744

[5]

ARRIZABALAGA P, 1986, CHEM PHYS LETT, V124, P549, DOI 10.1016/0009-2614(86)85074-6

[6] ELECTRON-SPIN RESONANCE-SPECTRA OF THE ONE-ELECTRON-REDUCTION PRODUCTS OF STANNIC CHLORIDE ADDUCTS OF BIS(DITHIOOXALATO)NICKELATE(II), BIS(DITHIOOXALATO)PALLADATE(II), AND BIS(DITHIOOXALATO)PLATINATE(II) COMPLEXES [J].

BOWMAKER, GA ;

BOYD, PDW ;

CAMPBELL, GK .

INORGANIC CHEMISTRY, 1982, 21 (09) :3565-3568

[7] METAL-COMPLEXES AS LIGANDS .2. SYNTHESIS, STRUCTURE DETERMINATION, AND BONDING CHARACTERISTICS OF CERTAIN TIN(IV) HALIDE ADDUCTS OF NICKEL(II) AND PALLADIUM(II) DITHIOOXALATO COMPLEXES [J].

COUCOUVANIS, D ;

BAENZIGER, NC ;

JOHNSON, SM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (12) :3875-3886

[8]

ESHTIAGHHOSSEINI H, 1981, J CHEM SOC CHEM COMM, P199, DOI 10.1039/c39810000199

[9] PARAMAGNETIC M(I) COMPLEXES GENERATED BY ELECTROCHEMICAL REDUCTION OF M(II) NICKEL, PALLADIUM, AND PLATINUM 1,2-DITHIOLATES [J].

GEIGER, WE ;

ALLEN, CS ;

MINES, TE ;

SENFTLEBER, FC .

INORGANIC CHEMISTRY, 1977, 16 (08) :2003-2008

[10]

HALL SR, 1990, XTAL30 USERS MANUAL