CHANGES OF THE CARBONYL STRETCHING SPECTRA WITH TEMPERATURE

被引：30

作者：

STRAUSS, HL

机构：

[1] Department of Chemistry, University of California, Berkeley

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 03期

关键词：

D O I：

10.1021/ja00029a017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that the apparent collapse or coalescence of carbonyl stretching bands of eta-4-norbornadiene tricarbonyl iron can be attributed to thermal motion of the carbonyls in one potential well. This explanation is in contrast to explanations involving motion between wells. The one-well explanation is also consistent with the expected time scales for all of the possible motions.

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页码：905 / 907

页数：3

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