SYNTHESIS AND MOLECULAR-WEIGHTS OF METAL (STYRENE-METHYL METHACRYLATE) COPOLYMER .3.

被引：5

作者：

CARDENAS, G ^{[1
]}

RETAMAL, C ^{[1
]}

KLABUNDE, KJ ^{[1
]}

机构：

[1] KANSAS STATE UNIV AGR & APPL SCI, DEPT CHEM, MANHATTAN, KS 66506 USA

来源：

POLYMER BULLETIN | 1992年 / 27卷 / 04期

关键词：

D O I：

10.1007/BF00309693

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Styrene-methyl methacrylate colloids were obtained by codeposition at -196-degrees-C of the monomer with metals, such as: Au, Pd, Cu, Ga, In, Sn and Bi. The colloids were polymerized with various amounts of initiator (AIBN) at 60-degrees-C and a wide range of viscosity average molecular weights (MBARv; 2.0 x 10(4)-1.9 x 10(5)) were obtained depending upon the metal used. The metal colloid concentrations are reported. The thermal stability and metal composition are also described. The copolymers of Au, Ge, Pd and Sn are stable even at 300-degrees-C. The metal content is 0.9 to 11% with an exception of 22% for Au.

引用

页码：383 / 388

页数：6

共 12 条

[1] DYNAMIC MIGRATION OF ORGANOMETALLIC GROUPS IN FREE-RADICAL ADDUCTS OF BENZIL [J].

ALBERTI, A ;

HUDSON, A .

CHEMICAL PHYSICS LETTERS, 1977, 48 (02) :331-333

[2]

BILLMEYER FW, 1962, TXB POLYM SCI, P290

[3] THERMOGRAVIMETRIC STUDIES OF METAL POLY(METHYL METHACRYLATES) [J].

CARDENAS, G ;

RETAMAL, C ;

TAGLE, LH .

THERMOCHIMICA ACTA, 1991, 176 :233-240

[4]

Cardenas-Trivino G., 1987, P SPIE INT SOC OPT E P SPIE INT SOC OPT E, V821, P206

[5]

CARDENASTRIVINO G, 1990, BOL SOC CHIL QUIM, V35, P223

[6]

CARDENASTRIVINO G, 1988, BOL SOC CHIL QUIM, V33, P163

[7] LIVING COLLOIDAL PALLADIUM IN NONAQUEOUS SOLVENTS - FORMATION, STABILITY, AND FILM-FORMING PROPERTIES - CLUSTERING OF METAL ATOMS IN ORGANIC MEDIA .14. [J].

CARDENASTRIVINO, G ;

KLABUNDE, KJ ;

DALE, EB .

LANGMUIR, 1987, 3 (06) :986-992

[8]

CARDENASTRIVINO G, 1990, BOL SOC CHIL QUIM, V35, P277

[9] SYNTHESIS AND MOLECULAR-WEIGHTS OF METAL POLY(METHYL METHACRYLATES) [J].

CARDENASTRIVINO, G ;

RETAMAL, C ;

KLABUNDE, KJ .

POLYMER BULLETIN, 1991, 25 (03) :315-318

[10] Colloidal Metal Particles Dispersed in Monomeric and Polymeric Styrene and Methyl Methacrylate [J].

Klabunde, Kenneth J. ;

Habdas, Jan ;

Cardenas-Trivino, Galo .

CHEMISTRY OF MATERIALS, 1989, 1 (05) :481-483

← 1 2 →