ALLYLATION OF QUINONES WITH ALLYLSILANE IN THE PRESENCE OF LITHIUM PERCHLORATE IN ETHER

被引：45

作者：

IPAKTSCHI, J

HEYDARI, A

机构：

[1] Institut Für Organische Chemie Universität Heinrich, Giessen, D-W-6300

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acidity and polarity of LiClO4/Et2O as a reaction medium are sufficient to cause the allylation of trisubstituted quinones with allyltrimethylsilane. A radical process with an electron-transfer step from a quinone/allylsilane charge-transfer complex is postulated for the reaction sequence. One product is 1, depicted to the right (R1 = CH3, R2 = R3 = OCH3).

引用

页码：313 / 314

页数：2

共 16 条

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