VALIDITY OF STEADY-STATE APPROXIMATION APPLIED TO PYROLYSIS OF N-BUTANE

被引:16
作者
BLAKEMORE, JE
CORCORAN, WH
机构
[1] California Institute of Technology, Pasadena
来源
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT | 1969年 / 8卷 / 02期
关键词
D O I
10.1021/i260030a009
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A quantitative proof of the validity of the steady-state approximation in the mechanistic treatment of the pyrolysis of n-butane is given. The length of the induction period is noted, and the free-radical concentrations are predicted. Rate constants used for the individual steps in the mechanism were developed from a careful review of the literature. © 1969, American Chemical Society. All rights reserved.
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页码:206 / +
页数:1
相关论文
共 19 条
[1]  
BARKER JR, UNPUBLISHED WORK
[2]   GAS KINETICS [J].
BENSON, SW ;
DEMORE, WB .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1965, 16 :397-+
[3]   HYDROGEN ATOM ABSTRACTION BY ETHYL-D5 RADICALS .1. [J].
BODDY, PJ ;
STEACIE, EWR .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1960, 38 (09) :1576-1589
[4]   THE MERCURY (P-3(1)) PHOTO-SENSITIZED REACTION OF ETHANE AT HIGH TEMPERATURES [J].
BYWATER, S ;
STEACIE, EWR .
JOURNAL OF CHEMICAL PHYSICS, 1951, 19 (03) :326-329
[5]   DEPARTURE FROM STEADY STATE IN CHAIN REACTIONS WITH 2 OR MORE RADICALS [J].
GIDDINGS, JC ;
SHIN, HK .
JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (03) :640-&
[6]   PSEUDOSTATIONARY STATE APPROXIMATION IN CHEMICAL KINETICS [J].
HIRSCHFELDER, JO .
JOURNAL OF CHEMICAL PHYSICS, 1957, 26 (02) :271-273
[7]   THE DISPROPORTIONATION AND COMBINATION OF ETHYL RADICALS - THE PHOTOLYSIS OF MERCURY DIETHYL [J].
IVIN, KJ ;
STEACIE, EWR .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1951, 208 (1092) :25-42
[8]   PHOTOLYSIS OF ACETONE-D6 IN PRESENCE OF PROPANE-2,2-D2 DECOMPOSITION OF N-PROPYL RADICAL [J].
JACKSON, WM ;
MCNESBY, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (24) :4891-&
[9]   THE REACTION OF METHYL RADICALS WITH ISOBUTANE [J].
JONES, MH ;
STEACIE, EWR .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1953, 31 (05) :505-510
[10]   THE REACTIONS OF ALKYL RADICALS .3. N-BUTYL RADICALS FROM THE PHOTOLYSIS OF N-VALERALDEHYDE [J].
KERR, JA ;
TROTMANDICKENSON, AF .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (APR) :1602-1608